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nmrlearner 03-02-2011 11:54 AM

Solid-state photo-CIDNP effect observed in phototropin LOV1-C57S by (13)C magic-angle spinning NMR spectroscopy.
 
Solid-state photo-CIDNP effect observed in phototropin LOV1-C57S by (13)C magic-angle spinning NMR spectroscopy.

Solid-state photo-CIDNP effect observed in phototropin LOV1-C57S by (13)C magic-angle spinning NMR spectroscopy.

J Am Chem Soc. 2010 Nov 10;132(44):15542-3

Authors: Thamarath SS, Heberle J, Hore PJ, Kottke T, Matysik J

Until now, the solid-state photo-CIDNP effect, discovered in 1994 by Zysmilich and McDermott, has been observed selectively in photosynthetic systems. Here we present the first observation of this effect in a nonphotosynthetic system, the blue-light photoreceptor phototropin LOV1-C57S using (13)C magic-angle spinning (MAS) NMR.

PMID: 20958069 [PubMed - indexed for MEDLINE]



Source: PubMed


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