Since the first pioneering studies on small deuterated peptides dating more than 20 years ago, ¹H detection has evolved into the most efficient approach for investigation of biomolecular structure, dynamics, and interactions by solid-state NMR. The development of faster and faster magic-angle spinning (MAS) rates (up to 150 kHz today) at ultrahigh magnetic fields has triggered a real revolution in the field. This new spinning regime reduces the ¹H-¹H dipolar couplings, so that a direct detection...
[NMR paper] Decoherence optimized tilted-angle cross polarization: A novel concept for sensitivity-enhanced solid-state NMR using ultra-fast magic angle spinning.
Decoherence optimized tilted-angle cross polarization: A novel concept for sensitivity-enhanced solid-state NMR using ultra-fast magic angle spinning.
http://www.bionmr.com//www.ncbi.nlm.nih.gov/corehtml/query/egifs/https:--linkinghub.elsevier.com-ihub-images-PubMedLink.gif Related Articles Decoherence optimized tilted-angle cross polarization: A novel concept for sensitivity-enhanced solid-state NMR using ultra-fast magic angle spinning.
J Magn Reson. 2020 Oct 27;322:106857
Authors: Matsunaga T, Matsuda I, Yamazaki T, Ishii Y
Abstract
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[NMR paper] Strategies for 1H-detected dynamic nuclear polarisation magic-angle spinning NMR.
Strategies for 1H-detected dynamic nuclear polarisation magic-angle spinning NMR.
Related Articles Strategies for 1H-detected dynamic nuclear polarisation magic-angle spinning NMR.
Chemistry. 2020 Aug 22;:
Authors: Concistré M, Paul S, Carravetta M, Kuprov I, Williamson PTF
Abstract
Combining dynamic nuclear polarization with proton detection significantly enhances the sensitivity of magic-angle spinning NMR. Here we demonstrate the feasibility of proton- detected experiments with slow (10 kHz) magic angle spinning. The...
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[NMR paper] Setting the magic angle for fast magic-angle spinning probes
Setting the magic angle for fast magic-angle spinning probes
Publication date: August 2018
Source: Journal of Magnetic Resonance, Volume 293
Author(s): Susanne Penzel, Albert A. Smith, Matthias Ernst, Beat H. Meier
Abstract
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Dynamic Nuclear Polarization-Enhanced Biomolecular NMR Spectroscopy at High Magnetic Field with Fast Magic-Angle Spinning #DNPNMR
From The DNP-NMR Blog:
Dynamic Nuclear Polarization-Enhanced Biomolecular NMR Spectroscopy at High Magnetic Field with Fast Magic-Angle Spinning #DNPNMR
Jaudzems, Kristaps, Andrea Bertarello, Sachin R. Chaudhari, Andrea Pica, Diane Cala-De Paepe, Emeline Barbet-Massin, Andrew J. Pell, et al. “Dynamic Nuclear Polarization-Enhanced Biomolecular NMR Spectroscopy at High Magnetic Field with Fast Magic-Angle Spinning.” Angewandte Chemie 0 (2018).
https://doi.org/10.1002/ange.201801016.
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[NMR paper] Setting the magic angle for fast magic-angle spinning probes
Setting the magic angle for fast magic-angle spinning probes
Publication date: Available online 15 June 2018
Source:Journal of Magnetic Resonance</br>
Author(s): Susanne Penzel, Albert A. Smith, Matthias Ernst, Beat H. Meier</br>
Fast magic-angle spinning, coupled with 1H detection is a powerful method to improve spectral resolution and signal to noise in solid-state NMR spectra. Commercial probes now provide spinning frequencies in excess of 100 kHz. Then, one has sufficient resolution in the 1H dimension to directly detect protons, which have a gyromagnetic...
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[NMR paper] Dynamic nuclear polarization enhanced biomolecular NMR spectroscopy at high magnetic field with fast magic-angle spinning.
Dynamic nuclear polarization enhanced biomolecular NMR spectroscopy at high magnetic field with fast magic-angle spinning.
Dynamic nuclear polarization enhanced biomolecular NMR spectroscopy at high magnetic field with fast magic-angle spinning.
Angew Chem Int Ed Engl. 2018 Mar 22;:
Authors: Jaudzems K, Bertarello A, Chaudhari SR, Pica A, Cala-De Paepe D, Barbet-Massin E, Pell AJ, Akopjana I, Kotelovica S, Gajan D, Ouari O, Tars K, Pintacuda G, Lesage A
Abstract
Dynamic nuclear polarization (DNP) represents a powerful way to...
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[NMR paper] Nano-Mole Scale Side-Chain Signal Assignment by 1H-Detected Protein Solid-State NMR by Ultra-Fast Magic-Angle Spinning and Stereo-Array Isotope Labeling.
Nano-Mole Scale Side-Chain Signal Assignment by 1H-Detected Protein Solid-State NMR by Ultra-Fast Magic-Angle Spinning and Stereo-Array Isotope Labeling.
http://www.bionmr.com//www.ncbi.nlm.nih.gov/corehtml/query/egifs/http:--www.plosone.org-images-pone_120x30.png Related Articles Nano-Mole Scale Side-Chain Signal Assignment by 1H-Detected Protein Solid-State NMR by Ultra-Fast Magic-Angle Spinning and Stereo-Array Isotope Labeling.
PLoS One. 2015;10(4):e0122714
Authors: Wang S, Parthasarathy S, Nishiyama Y, Endo Y, Nemoto T, Yamauchi K, Asakura T,...
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[NMR paper] Rapid proton-detected NMR assignment for proteins with fast magic angle spinning.
Rapid proton-detected NMR assignment for proteins with fast magic angle spinning.
Rapid proton-detected NMR assignment for proteins with fast magic angle spinning.
J Am Chem Soc. 2014 Aug 7;
Authors: Barbet-Massin E, Pell AJ, Retel J, Andreas LB, Jaudzems K, Franks WT, Nieuwkoop AJ, Hiller M, Higman VA, Guerry P, Bertarello A, Knight MJ, Felletti M, Le Marchand T, Kotelovica S, Akopjana I, Tars K, Stoppini M, Bellotti V, Bolognesi M, Ricagno S, Chou JJ, Griffin RG, Oschkinat H, Lesage A, Emsley L, Herrmann T, Pintacuda G
Abstract
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1H-Detected Biomolecular NMR under Fast Magic-Angle Spinning
Linear Mode
