View Single Post
  #2  
Unread 07-16-2013, 03:32 PM
nmr@sks nmr@sks is offline
Junior Member
 
Join Date: Jun 2011
Posts: 1
Points: 10, Level: 1
Points: 10, Level: 1 Points: 10, Level: 1 Points: 10, Level: 1
Level up: 19%, 40 Points needed
Level up: 19% Level up: 19% Level up: 19%
Activity: 0%
Activity: 0% Activity: 0% Activity: 0%
NMR Credits: 0
NMR Points: 0
Downloads: 0
Uploads: 0
Default

it may take years to acquire a good resolution 5D spectrum using conventional sampling. Moreover a full 5D spectrum is a huge file (usually in T bytes) and its hard to navigate through such file for analysis. However..you can use time efficient acquisition by employing non-uniform sampling (NUS), also named as random or non-linear sampling. NUS data acquisition omits significant number of sampling points during the experiment and reconstruct them later. Because these methods require data sampled at uniform intervals, a two- to three-fold reduction in acquisition time can routinely be realized for each indirect time dimension that employs non uniform sampling.

For analysis..following may help.
TSAR: a program for automatic resonance assignment using 2D cross-sections of high dimensionality, high-resolution spectra - Springer
Reply With Quote


Did you find this post helpful? Yes | No